A. Qomi, M. J. Krakowiak, K. J. Bauchy, M. Stewart, K. L. Shahsavari et al., Combinatorial molecular optimization of cement hydrates, Nature Communications, vol.56, p.4960, 2014.
DOI : 10.1016/j.jmps.2007.06.011

M. D. Andersen, H. J. Jakobsen, and J. Skibsted, Si MAS NMR Investigation, Inorganic Chemistry, vol.42, issue.7, pp.2280-2287, 2003.
DOI : 10.1021/ic020607b

T. T. Bach, E. Chabas, I. Pochard, C. Cau-dit-coumes, J. Haas et al., Retention of alkali ions by hydrated low-pH cements: Mechanism and Na+/K+ selectivity, Cement and Concrete Research, vol.51, pp.14-21, 2013.
DOI : 10.1016/j.cemconres.2013.04.010

D. L. Bish and J. E. Post, Editors. Modern Powder Diffraction, 1990.

P. Blanc, X. Bourbon, A. Lassin, and E. C. Gaucher, Chemical model for cement-based materials: Temperature dependence of thermodynamic functions for nanocrystalline and crystalline C???S???H phases, Cement and Concrete Research, vol.40, issue.6, pp.851-866, 2010.
DOI : 10.1016/j.cemconres.2009.12.004
URL : https://hal.archives-ouvertes.fr/hal-00561050

E. Bonaccorsi, S. Merlino, and A. R. Kampf, The Crystal Structure of Tobermorite 14 A (Plombierite), a C-S-H Phase, Journal of the American Ceramic Society, vol.79, issue.3, pp.505-512, 2005.
DOI : 10.1002/zaac.19683600511

G. W. Brindley and G. Brown, Editors. Crystal Structures of Clay Minerals and Their X-ray Identification, 1980.

C. J. Brinker, R. J. Kirkpatrick, D. R. Tallant, B. C. Bunker, and B. Montez, NMR confirmation of strained ???defects??? in amorphous silica, Journal of Non-Crystalline Solids, vol.99, issue.2-3, pp.418-428, 1988.
DOI : 10.1016/0022-3093(88)90448-6

S. Brunauer and S. A. Greenberg, Chemistry of Cement, Proceedings of the Fourth International Symposium, 1960.

F. Brunet, P. Bertani, T. Charpentier, A. Nonat, and J. Virlet, Si Heteronuclear NMR Correlation to Structural Studies of Calcium Silicate Hydrates, The Journal of Physical Chemistry B, vol.108, issue.40, pp.15494-15502, 2004.
DOI : 10.1021/jp031174g

W. R. Busing and H. A. Levy, Neutron Diffraction Study of Calcium Hydroxide, The Journal of Chemical Physics, vol.87, issue.3, pp.563-568, 1957.
DOI : 10.1063/1.1749634

S. Chatterji, Comment on "Mesostructure of Calcium Silicate Hydrate (C-S-H) Gels in Portland Cement Paste: Short-Range Ordering, Nanocrystallinity, and Local Compositional Order", Journal of the American Ceramic Society, vol.69, issue.7, pp.2959-2960, 1997.
DOI : 10.1111/j.1151-2916.1997.tb03220.x

S. V. Churakov, Structural position of H2O molecules and hydrogen bonding in anomalous 11 A tobermorite, American Mineralogist, vol.94, issue.1, pp.156-165, 2009.
DOI : 10.2138/am.2009.2907

S. V. Churakov, Structure of the interlayer in normal 11 ?? tobermorite from an ab initio study, European Journal of Mineralogy, vol.21, issue.1, pp.261-271, 2009.
DOI : 10.1127/0935-1221/2009/0021-1865

S. V. Churakov, C. Labbez, L. Pegado, and M. Sulpizi, Intrinsic Acidity of Surface Sites in Calcium Silicate Hydrates and Its Implication to Their Electrokinetic Properties, The Journal of Physical Chemistry C, vol.118, issue.22, pp.11752-11762, 2014.
DOI : 10.1021/jp502514a

X. Cong and R. J. Kirkpatrick, 29Si and 17O NMR investigation of the structure of some crystalline calcium silicate hydrates, Advanced Cement Based Materials, vol.3, issue.3-4, pp.133-143, 1996.
DOI : 10.1016/S1065-7355(96)90045-0

X. Cong and R. J. Kirkpatrick, 29Si MAS NMR study of the structure of calcium silicate hydrate, Advanced Cement Based Materials, vol.3, issue.3-4, pp.144-156, 1996.
DOI : 10.1016/S1065-7355(96)90046-2

V. A. Drits, B. A. Sakharov, A. L. Salyn, and A. Manceau, Clay Miner, pp.185-207, 1993.

V. A. Drits and C. Tchoubar, X-ray Diffraction by Disordered Lamellar Structures: Theory and Applications to Microdivided Silicates and Carbons, 1990.
DOI : 10.1007/978-3-642-74802-8

M. A. Etzold, P. J. Mcdonald, and A. F. Routh, Growth of sheets in 3D confinements ??? a model for the C???S???H meso structure, Cement and Concrete Research, vol.63, pp.137-142, 2014.
DOI : 10.1016/j.cemconres.2014.05.001

P. Faucon, T. Charpentier, A. Nonat, and J. C. Petit, Al Magic Angle Nuclear Magnetic Resonance Study of the Aluminum Incorporation in Calcium Silicate Hydrates, Journal of the American Chemical Society, vol.120, issue.46, pp.12075-12082, 1998.
DOI : 10.1021/ja9806940

P. Faucon, A. Delagrave, C. Richet, J. M. Marchand, and H. Zanni, Aluminum Incorporation in Calcium Silicate Hydrates (C???S???H) Depending on Their Ca/Si Ratio, The Journal of Physical Chemistry B, vol.103, issue.37, pp.7796-7802, 1999.
DOI : 10.1021/jp990609q

R. F. Feldman and P. J. Sereda, A model for hydrated Portland cement paste as deduced from sorption-length change and mechanical properties, Mat??riaux et Constructions, vol.49, issue.6, pp.509-520, 1968.
DOI : 10.1007/BF02473639

K. Garbev, G. Beuchle, M. Bornefeld, L. Black, and P. Stemmermann, Cell Dimensions and Composition of Nanocrystalline Calcium Silicate Hydrate Solid Solutions. Part 1: Synchrotron-Based X-Ray Diffraction, Journal of the American Ceramic Society, vol.13, issue.[3], pp.3005-3014, 2008.
DOI : 10.1111/j.1551-2916.2008.02484.x

K. Garbev, M. Bornefeld, G. Beuchle, and P. Stemmermann, Cell Dimensions and Composition of Nanocrystalline Calcium Silicate Hydrate Solid Solutions. Part 2: X-Ray and Thermogravimetry Study, Journal of the American Ceramic Society, vol.360, issue.[9], pp.3015-3023, 2008.
DOI : 10.1111/j.1551-2916.2008.02601.x

W. P. Gates, P. G. Slade, A. Manceau, and B. Lanson, Site Occupancies by Iron in Nontronites, Clays and Clay Minerals, vol.50, issue.2, pp.223-239, 2002.
DOI : 10.1346/000986002760832829

S. Grangeon, F. Claret, C. Lerouge, F. Warmont, T. Sato et al., On the nature of structural disorder in calcium silicate hydrates with a calcium/silicon ratio similar to tobermorite, Cement and Concrete Research, vol.52, pp.31-37, 2013.
DOI : 10.1016/j.cemconres.2013.05.007
URL : https://hal.archives-ouvertes.fr/hal-01024533

S. Grangeon, B. Lanson, M. Lanson, and A. Manceau, Crystal structure of Ni-sorbed synthetic vernadite: a powder X-ray diffraction study, Mineralogical Magazine, vol.72, issue.6, pp.1279-1291, 2008.
DOI : 10.1180/minmag.2008.072.6.1279
URL : https://hal.archives-ouvertes.fr/insu-00404407

S. Grangeon, B. Lanson, N. Miyata, Y. Tani, and A. Manceau, Structure of nanocrystalline phyllomanganates produced by freshwater fungi, American Mineralogist, vol.95, issue.11-12, pp.1608-1616, 2010.
DOI : 10.2138/am.2010.3516
URL : https://hal.archives-ouvertes.fr/insu-00544688

S. Grangeon, A. Manceau, J. Guilhermet, A. Gaillot, M. Lanson et al., Zn sorption modifies dynamically the layer and interlayer structure of vernadite, Geochimica et Cosmochimica Acta, vol.85, pp.302-313, 2012.
DOI : 10.1016/j.gca.2012.02.019
URL : https://hal.archives-ouvertes.fr/hal-00866457

G. W. Groves, P. J. Sueur, and W. Sinclair, Transmission Electron Microscopy and Microanalytical Studies of Ion-Beam-Thinned Sections of Tricalcium Silicate Paste, Journal of the American Ceramic Society, vol.15, issue.4, pp.353-356, 1986.
DOI : 10.1111/j.1151-2916.1986.tb04746.x

J. Hadi, S. Grangeon, F. Warmont, A. Seron, and J. Greneche, A novel and easy chemical-clock synthesis of nanocrystalline iron???cobalt bearing layered double hydroxides, Journal of Colloid and Interface Science, vol.434, pp.130-140, 2014.
DOI : 10.1016/j.jcis.2014.07.029
URL : https://hal.archives-ouvertes.fr/hal-01071777

L. Heller and H. F. Taylor, Crystallographic Data for the Calcium Silicates. London: Her Majesty's Stationery Office, 1956.

H. M. Jennings, Refinements to colloid model of C-S-H in cement: CM-II, Cement and Concrete Research, vol.38, issue.3, pp.275-289, 2008.
DOI : 10.1016/j.cemconres.2007.10.006

J. J. Kim, E. M. Foley, and M. M. Reda-taha, Nano-mechanical characterization of synthetic calcium???silicate???hydrate (C???S???H) with varying CaO/SiO2 mixture ratios, Cement and Concrete Composites, vol.36, pp.65-70, 2013.
DOI : 10.1016/j.cemconcomp.2012.10.001

R. J. Kirkpatrick, J. L. Yarger, P. F. Mcmillan, Y. Ping, and X. Cong, Raman spectroscopy of C-S-H, tobermorite, and jennite, Advanced Cement Based Materials, vol.5, issue.3-4, pp.93-99, 1997.
DOI : 10.1016/S1065-7355(97)00001-1

A. Korpa and R. Trettin, The influence of different drying methods on cement paste microstructures as reflected by gas adsorption: Comparison between freeze-drying (F-drying), D-drying, P-drying and oven-drying methods, Cement and Concrete Research, vol.36, issue.4, pp.634-649, 2006.
DOI : 10.1016/j.cemconres.2005.11.021

D. A. Kulik and M. Kersten, Aqueous Solubility Diagrams for Cementitious Waste Stabilization Systems: II, End-Member Stoichiometries of Ideal Calcium Silicate Hydrate Solid Solutions, Journal of the American Ceramic Society, vol.69, issue.12, pp.3017-3026, 2001.
DOI : 10.2475/ajs.281.10.1249

C. Labbez, B. Jö-nsson, I. Pochard, A. Nonat, and B. Cabane, Surface Charge Density and Electrokinetic Potential of Highly Charged Minerals:?? Experiments and Monte Carlo Simulations on Calcium Silicate Hydrate, The Journal of Physical Chemistry B, vol.110, issue.18, pp.9219-9230, 2006.
DOI : 10.1021/jp057096+
URL : https://hal.archives-ouvertes.fr/hal-00067903

C. Labbez, A. Nonat, I. Pochard, and B. Jö-nsson, Experimental and theoretical evidence of overcharging of calcium silicate hydrate, Journal of Colloid and Interface Science, vol.309, issue.2, pp.303-307, 2007.
DOI : 10.1016/j.jcis.2007.02.048
URL : https://hal.archives-ouvertes.fr/hal-00402986

S. Leonardelli, L. Facchini, C. Fretigny, P. Tougne, and A. P. Legrand, Silicon-29 NMR study of silica, Journal of the American Chemical Society, vol.114, issue.16, pp.6412-6418, 1992.
DOI : 10.1021/ja00042a018

N. Lequeux, A. Morau, S. Philippot, and P. Boch, Extended X-ray Absorption Fine Structure Investigation of Calcium Silicate Hydrates, Journal of the American Ceramic Society, vol.79, issue.7, pp.1299-1306, 1999.
DOI : 10.1680/adcr.1997.9.33.31

T. Maeshima, H. Noma, M. Sakiyama, and T. Mitsuda, Natural 1.1 and 1.4 nm tobermorites from Fuka, Okayama, Japan, Cement and Concrete Research, vol.33, issue.10, pp.1515-1523, 2003.
DOI : 10.1016/S0008-8846(03)00099-1

M. Magi, E. Lippmaa, A. Samoson, G. Engelhardt, and A. R. Grimmer, Solid-state high-resolution silicon-29 chemical shifts in silicates, The Journal of Physical Chemistry, vol.88, issue.8, pp.1518-1522, 1984.
DOI : 10.1021/j150652a015

A. Manceau, M. A. Marcus, S. Grangeon, M. Lanson, B. Lanson et al., Short-range and long-range order of phyllomanganate nanoparticles determined using high-energy X-ray scattering, Journal of Applied Crystallography, vol.81, issue.1, pp.193-209, 2013.
DOI : 10.1107/S0021889812047917/rg5022sup7.pdf
URL : https://hal.archives-ouvertes.fr/hal-00981389

H. Manzano, J. S. Dolado, A. Guerrero, and A. Ayuela, Mechanical properties of crystalline calcium-silicate-hydrates: comparison with cementitious C-S-H gels, physica status solidi (a), vol.34, issue.5, pp.1775-1780, 2007.
DOI : 10.1016/0001-6160(73)90064-3

M. A. Marcus, A. A. Macdowell, R. Celestre, A. Manceau, T. Miller et al., Beamline 10.3.2 at ALS: a hard X-ray microprobe for environmental and materials sciences, Journal of Synchrotron Radiation, vol.11, issue.3, pp.239-247, 2004.
DOI : 10.1107/S0909049504005837

N. C. Marty, S. Grangeon, F. Warmont, and C. Lerouge, Alteration of nanocrystalline calcium silicate hydrate (C-S-H) at pH 9.2 and room temperature: a combined mineralogical and chemical study, Mineralogical Magazine, vol.79, issue.2, pp.437-458, 2015.
DOI : 10.1180/minmag.2015.079.2.20
URL : https://hal.archives-ouvertes.fr/hal-01020487

D. Massiot, F. Fayon, M. Capron, I. King, L. Calvé et al., Modelling one- and two-dimensional solid-state NMR spectra, Magnetic Resonance in Chemistry, vol.320, issue.1, pp.70-76, 2002.
DOI : 10.1016/S0009-2614(00)00277-3

H. Matsuyama and J. F. Young, Effects of pH on precipitation of quasi-crystalline calcium silicate hydrate in aqueous solution, Advances in Cement Research, vol.12, issue.1, pp.29-33, 2000.
DOI : 10.1680/adcr.2000.12.1.29

S. Merlino, E. Bonaccorsi, and T. Armbruster, Tobermorites; their real structure and order-disorder (OD) character, American Mineralogist, vol.84, issue.10, pp.1613-1621, 1999.
DOI : 10.2138/am-1999-1015

S. Merlino, E. Bonaccorsi, and T. Armbruster, The real structure of tobermorite 11??: normal and anomalous forms, OD character and polytypic modifications, European Journal of Mineralogy, vol.13, issue.3, pp.577-590, 2001.
DOI : 10.1127/0935-1221/2001/0013-0577

F. M. Michel, J. Macdonald, J. Feng, B. L. Phillips, L. Ehm et al., Structural Characteristics of Synthetic Amorphous Calcium Carbonate, Chemistry of Materials, vol.20, issue.14, pp.4720-4728, 2008.
DOI : 10.1021/cm800324v

D. M. Moore and R. C. Reynolds, X-ray Diffraction and the Identification and Analysis of Clay Minerals, 1989.

R. J. Myers, S. A. Bernal, and J. L. Provis, A thermodynamic model for C-(N-)A-S-H gel: CNASH_ss. Derivation and validation, Cement and Concrete Research, vol.66, pp.27-47, 2014.
DOI : 10.1016/j.cemconres.2014.07.005

R. J. Myers, S. A. Bernal, R. San-nicolas, and J. L. Provis, Generalized Structural Description of Calcium???Sodium Aluminosilicate Hydrate Gels: The Cross-Linked Substituted Tobermorite Model, Langmuir, vol.29, issue.17, pp.5294-5306, 2013.
DOI : 10.1021/la4000473

R. J. Myers, E. Hô-pital, J. L. Provis, and B. Lothenbach, Effect of temperature and aluminium on calcium (alumino)silicate hydrate chemistry under equilibrium conditions, Cement and Concrete Research, vol.68, pp.83-93, 2015.
DOI : 10.1016/j.cemconres.2014.10.015

H. Noma, Y. Adachi, H. Yamada, T. Nishino, Y. Matsuda et al., Nuclear Magnetic Resonance Spectroscopy of Cement-Based Materials, 1998.

A. Nonat, The structure and stoichiometry of C-S-H, Cement and Concrete Research, vol.34, issue.9, pp.1521-1528, 2004.
DOI : 10.1016/j.cemconres.2004.04.035

X. Pardal, F. Brunet, T. Charpentier, I. Pochard, and A. Nonat, Si Solid-State NMR Characterization of Calcium-Aluminosilicate-Hydrate, Inorganic Chemistry, vol.51, issue.3, pp.1827-1836, 2012.
DOI : 10.1021/ic202124x
URL : https://hal.archives-ouvertes.fr/hal-00760310

L. Pegado, C. Labbez, and S. V. Churakov, Mechanism of aluminium incorporation into C???S???H from ab initio calculations, J. Mater. Chem. A, vol.205, issue.10, pp.3477-3483, 2014.
DOI : 10.1002/pssa.200778175

A. Plançon, Diffraction by layer structures containing different kinds of layers and stacking faults, Journal of Applied Crystallography, vol.14, issue.5, pp.300-304, 1981.
DOI : 10.1107/S0021889881009424

A. Plançon, : a program for calculating the diffraction by disordered lamellar structures, Journal of Applied Crystallography, vol.35, issue.3, p.377, 2002.
DOI : 10.1107/S0021889802001449

G. Renaudin, J. Russias, F. Leroux, F. Frizon, and C. Cau-dit-coumes, Structural characterization of C???S???H and C???A???S???H samples???Part I: Long-range order investigated by Rietveld analyses, Journal of Solid State Chemistry, vol.182, issue.12, pp.3312-3319, 2009.
DOI : 10.1016/j.jssc.2009.09.026

R. C. Reynolds, Acta Cryst, pp.319-320, 1968.

R. C. Reynolds, Clays Clay Miner, pp.359-367, 1986.

I. G. Richardson, The nature of C-S-H in hardened cements, Cement and Concrete Research, vol.29, issue.8, pp.1131-1147, 1999.
DOI : 10.1016/S0008-8846(99)00168-4

I. G. Richardson, Tobermorite/jennite- and tobermorite/calcium hydroxide-based models for the structure of C-S-H: applicability to hardened pastes of tricalcium silicate, ??-dicalcium silicate, Portland cement, and blends of Portland cement with blast-furnace slag, metakaolin, or silica fume, Cement and Concrete Research, vol.34, issue.9, pp.1733-1777, 2004.
DOI : 10.1016/j.cemconres.2004.05.034

I. G. Richardson, The calcium silicate hydrates, Cement and Concrete Research, vol.38, issue.2, pp.137-158, 2008.
DOI : 10.1016/j.cemconres.2007.11.005

I. G. Richardson, Acta Cryst, pp.903-923, 2014.

I. G. Richardson, A. R. Brough, G. W. Groves, and C. M. Dobson, The characterization of hardened alkali-activated blast-furnace slag pastes and the nature of the calcium silicate hydrate (C-S-H) phase, Cement and Concrete Research, vol.24, issue.5, pp.813-829, 1994.
DOI : 10.1016/0008-8846(94)90002-7

I. G. Richardson and G. W. Groves, Models for the composition and structure of calcium silicate hydrate (C???S???H) gel in hardened tricalcium silicate pastes, Cement and Concrete Research, vol.22, issue.6, pp.1001-1010, 1992.
DOI : 10.1016/0008-8846(92)90030-Y

I. G. Richardson and G. W. Groves, Microstructure and microanalysis of hardened cement pastes involving ground granulated blast-furnace slag, Journal of Materials Science, vol.1, issue.22, pp.6204-6212, 1992.
DOI : 10.1007/BF01133772

I. G. Richardson and G. W. Groves, Microstructure and microanalysis of hardened ordinary Portland cement pastes, Journal of Materials Science, vol.13, issue.1, pp.265-277, 1993.
DOI : 10.1007/BF00349061

C. Roosz, S. Grangeon, P. Blanc, V. Montouillout, B. Lothenbach et al., Crystal structure of magnesium silicate hydrates (M-S-H): The relation with 2:1 Mg???Si phyllosilicates, Cement and Concrete Research, vol.73, pp.228-237, 2015.
DOI : 10.1016/j.cemconres.2015.03.014
URL : https://hal.archives-ouvertes.fr/hal-01356812

B. A. Sakharov and B. Lanson, Handbook of Clay Science, pp.51-136, 2013.

F. E. Sowrey, L. J. Skipper, D. M. Pickup, K. O. Drake, Z. Lin et al., Systematic empirical analysis of calcium???oxygen coordination environment by calcium K-edge XANES, Phys. Chem. Chem. Phys., vol.39, issue.2, pp.188-192, 2004.
DOI : 10.1107/S0108270183008392

S. Soyer-uzun, S. R. Chae, C. J. Benmore, H. Wenk, and P. J. Monteiro, Compositional Evolution of Calcium Silicate Hydrate (C-S-H) Structures by Total X-Ray Scattering, Journal of the American Ceramic Society, vol.82, issue.3, pp.793-798, 2012.
DOI : 10.1103/PhysRevB.82.224202

D. Sugiyama, Chemical alteration of calcium silicate hydrate (C???S???H) in sodium chloride solution, Cement and Concrete Research, vol.38, issue.11, pp.1270-1275, 2008.
DOI : 10.1016/j.cemconres.2008.06.002

H. F. Taylor, Proposed Structure for Calcium Silicate Hydrate Gel, Journal of the American Ceramic Society, vol.13, issue.2, pp.464-467, 1986.
DOI : 10.2465/ganko1941.79.267

H. F. Taylor and J. W. Howison, Relationships Between Calcium Silicates and Clay Minerals, Clay Minerals, vol.3, issue.16, pp.98-111, 1956.
DOI : 10.1180/claymin.1956.003.16.06
URL : http://www.minersoc.org/pages/Archive-CM/Volume_3/3-16-98.pdf

M. Vandamme and F. J. Ulm, Nanoindentation investigation of creep properties of calcium silicate hydrates, Cement and Concrete Research, vol.52, pp.38-52, 2013.
DOI : 10.1016/j.cemconres.2013.05.006
URL : https://hal.archives-ouvertes.fr/hal-00840477

H. Viallis, P. Faucon, J. C. Petit, and A. Nonat, Interaction between Salts (NaCl, CsCl) and Calcium Silicate Hydrates (C???S???H), The Journal of Physical Chemistry B, vol.103, issue.25, pp.5212-5219, 1999.
DOI : 10.1021/jp983757+

D. Viehland, J. F. Li, L. J. Yuan, and Z. K. Xu, Mesostructure of Calcium Silicate Hydrate (C-S-H) Gels in Portland Cement Paste: Short-Range Ordering, Nanocrystallinity, and Local Compositional Order, Journal of the American Ceramic Society, vol.4, issue.7, pp.1731-1744, 1996.
DOI : 10.1016/0008-8846(94)90043-4

B. E. Warren, X-Ray Diffraction in Random Layer Lattices, Physical Review, vol.166, issue.9, pp.693-698, 1941.
DOI : 10.1103/PhysRev.59.693

P. Yu, R. J. Kirkpatrick, B. Poe, P. F. Mcmillan, and X. Cong, Structure of Calcium Silicate Hydrate (C-S-H): Near-, Mid-, and Far-Infrared Spectroscopy, Journal of the American Ceramic Society, vol.18, issue.12, pp.742-748, 1999.
DOI : 10.1180/mono-4.9

X. Zhang, W. Chang, T. Zhang, and C. K. Ong, Nanostructure of Calcium Silicate Hydrate Gels in Cement Paste, Journal of the American Ceramic Society, vol.80, issue.12, pp.2600-2604, 2000.
DOI : 10.1111/j.1151-2916.2000.tb01595.x