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Communication dans un congrès

Structure of nanocrystalline calcium silicate hydrates

Abstract : Nanocrystalline calcium silicate hydrates (C-S-H) are the main hydration products and the main binging phases in many types of cement, including ordinary Portland cement. As a result of its ubiquity is these engineered systems, C-S-H controls main cement physical and chemical properties. These properties depend on C-S-H calcium to silicon atomic ratio (Ca/Si), which is commonly described as ranging between 0.6 and 2.3. This means that C-S-H structure dictates cement macroscopic properties. As a consequence, its crystal-chemistry must be understood to be able to understand (and thus predict) cement properties. However, despites decades of study, its crystal structure is still a matter of debate. Depending on the authors and on the calcium to silicon ratio, the structure is described similar to one or more of the following minerals: tobermorite, jennite and possibly portlandite. Such inaccuracy largely results from its X-ray diffraction patterns, which exhibits only a few weak and mostly asymmetrical diffraction maxima and thus cannot be refined using classical methods. By using a specific formalism for the analysis of X-ray diffraction patterns, previously applied to phyllosilicates and phyllomanganates, it is here proposed that C-S-H can be described as a lamellar structure similar to nanocrystalline and turbostratic tobermorite, turbostratism meaning that there is the systematic presence, between adjacent layers, of a random rotation about the normal to the layers and/or a random translation in the layer plane. This model was validated using complementary methods (including transmission electron microscopy, synchrotron X-ray absorption spectroscopy and synchrotron high-energy X-ray scattering). From analysis of literature data, it is proposed that the evolution of C-S-H structure as a function of Ca/Si can be described as interstratification of two different types of layers having calcium to silicon ratios of 0.6 and 1.25, plus discrete Ca(OH)2 at higher ratios.
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Communication dans un congrès
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https://hal-brgm.archives-ouvertes.fr/hal-01019307
Contributeur : Sylvain Grangeon <>
Soumis le : lundi 7 juillet 2014 - 10:50:22
Dernière modification le : lundi 20 juillet 2020 - 11:02:02
Archivage à long terme le : : mardi 7 octobre 2014 - 11:53:00

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C-S-H_MECC_2014.pdf
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  • HAL Id : hal-01019307, version 1

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Sylvain Grangeon, Francis Claret, Catherine Lerouge, Bruno Lanson. Structure of nanocrystalline calcium silicate hydrates. 7th Mid-European Clay Conference : MECC14, Sep 2014, Dresden, Germany. ⟨hal-01019307⟩

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