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Article Dans Une Revue Environmental Science and Pollution Research Année : 2013

Polar organic chemical integrative sampler (POCIS) uptake rates for 17 polar pesticides and degradation products: laboratory calibration

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Résumé

Polar organic chemical integrative samplers (POCIS) are useful for monitoring a wide range of chemicals, including polar pesticides, in water bodies. However, few calibration data are available, which limits the use of these samplers for time-weighted average concentration measurements in an aquatic medium. This work deals with the laboratory calibration of the pharmaceutical configuration of a polar organic chemical integrative sampler (pharm-POCIS) for calculating the sampling rates of 17 polar pesticides (1.15 ≤ logK ow ≤ 3.71) commonly found in water. The experiment, conducted for 21 days in a continuous water flow-through exposure system, showed an integrative accumulation of all studied pesticides for 15 days. Three compounds (metalaxyl, azoxystrobine, and terbuthylazine) remained integrative for the 21-day experiment. The sampling rates measured ranged from 67.9 to 279 mL day−1 and increased with the hydrophobicity of the pesticides until reaching a plateau where no significant variation in sampling rate is observed when increasing the hydrophobicity.
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Dates et versions

hal-00749855 , version 1 (08-11-2012)
hal-00749855 , version 2 (14-08-2013)

Identifiants

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Imtiaz Ibrahim, Anne Togola, Catherine Gonzalez. Polar organic chemical integrative sampler (POCIS) uptake rates for 17 polar pesticides and degradation products: laboratory calibration. Environmental Science and Pollution Research, 2013, 20 (6), pp.3679-3687. ⟨10.1007/s11356-012-1284-3⟩. ⟨hal-00749855v2⟩
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