A study on the influence of nanofluids on gas hydrate formation kinetics and their potential: Application to the CO₂ capture process

Samer Said (1) , Varun Govindaraj (2) , Jean-Michel Herri (3, 4, 5) , Yamina Ouabbas (3, 4, 5) , Mohamed Khodja (6) , Mohamed Belloum (1) , Jitendra S. Sangwai (7) , Ramamurthy Nagarajan (2)

1 LCMVAR - Laboratory of Materials Chemistry and the Living
2 Department of Chemical Engineering [Chennai]
3 LGF-ENSMSE - Laboratoire Georges Friedel
4 PROPICE-ENSMSE - Département PROcédés Poudres, Interfaces, Cristallisation et Ecoulements
5 SPIN-ENSMSE - Centre Sciences des Processus Industriels et Naturels
6 SONATRACH
7 Gas Hydrate and Flow Assurance Laboratory, Petroleum Engineering Program, Department of Ocean Engineering

In this work, the effects of Al₂O₃, SiO₂, Ag and Cu nanoparticles on the kinetics of CO₂-CH₄ hydrate formation process were experimentally studied by measuring the amount of gas consumed and the rate of gas consumption. A suspension of 0.1wt%, 0.2wt % and 0.3wt% of each nanoparticle was injected into the hydrate formation reactor, while pressure and temperature were maintained at 4.0 MPa and 274.15 K, and the magnetic stirrer speed was set at 350 rpm. The CO₂-CH₄ hydrate formation process was studied in both pure water and water containing a 0.1wt%, 0.2wt% and 0.3wt% of each nanoparticle suspension. The results showed that these nanoparticles had a positive effect on hydrate formation. These effects varied from one nanoparticle to another. It was observed that nanoparticles of SiO₂ had the most positive effect on CO₂ gas consumption, particularly at a concentration of 0.3wt%. At this concentration the average amount of gas consumed was about 45% higher than that in pure water during the dissolution and 77% during crystallization. Cu and Al₂O₃ nanoparticles had an intermediate effect with improvement in gas consumption by 1% to 15% during dissolution; while it had an important impact on gas consumption during hydrate crystallization with an improvement of 30% to 65%. Ag nanoparticles had no significant effect during these two phases

Mots clés: Gas hydrates; Nanoparticles; Kinetics; CO₂

Domaines: Génie des procédés

Samer Said, Varun Govindaraj, Jean-Michel Herri, Yamina Ouabbas, Mohamed Khodja, et al.. A study on the influence of nanofluids on gas hydrate formation kinetics and their potential: Application to the CO₂ capture process. Journal of Natural Gas Science and Engineering, 2016, 32, pp.95-108. ⟨10.1016/j.jngse.2016.04.003⟩. ⟨hal-01346311⟩